Product ID:PLMN2-3X, CUSTOM PLASMA STANDARD, 10,000 PPM (SUPDAT)
MSDS Date:04/15/1996
FSC:6810
NIIN:00N043867
MSDS Number: CHCDT

SPEX CERTIPREP

203 NORCROSS AVE
METUCHEN, NJ 08840
US

Emergency Phone: 800-424-9300 (CHEMTREC)

Info Phone: 908-549-7144

Preparer: SUSHA RAMANE

Cage: 04XT3

SPEX CERTIPREP INC

METUCHEN, NJ 08840 US

Telephone: 732-549-7144

Cage: 04XT3

OF BREATH, HEADACHE, NAUSEA AND VOMITING.

RTECS: 9999999ZZ

NITRIC ACID; (HNO*3) (SARA 302/313) (CERCLA)

CAS: 7697-37-2

RTECS: QU5775000

Fraction By Weight: 2-5%

OSHA PEL 2 PPM

ACGIH TLV: 2 PPM;4 STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

MANGANESE(III) ACETATE DIHYDRATE; (MN(C2H3O2)3-2H2O).

CAS: 19513-05-4

Fraction By Weight: <4.9%

OSHA PEL N/K

ACGIH TLV: 5 MG/M3 (MN) (MFR)

WATER

CAS: 7732-18-5

RTECS: ZC0110000

Fraction By Weight: 80-90%

OSHA PEL N/K

ACGIH TLV: N/K

SULFIDE, ETC. CONTACT W/STRONG BASES WILL CAUSE

RTECS: 9999999ZZ

IMMED, SEV & PENETRATING BURNS; CONC SOLNS

RTECS: 9999999ZZ

YELLOWISH BROWN COLOR. VAP & MIST MAY ERODE EXPOS

RTECS: 9999999ZZ

& BURNS OF MOUTH, ESOPHAGUS & GI TRACT. INHAL MAY BE

RTECS: 9999999ZZ

BRONCHI, CHEM PNEUM & PULM EDEMA. SYMPS INCL; BURNING

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:SYMPS & HLTH HAZS FOR DILUTE NITRIC
ACID ARE EXPECTED TO BE LESS SEV THAN EXPOS TO CONC NITRIC ACID.
HOWEVER, SINCE NITRIC ACID IS IN SOLN AT 1% OR GREATER, HLTH HAZS
FOR CONC NITRIC ACID ARE GIVEN. T HIS SOLN MAY BE HARMFUL IF
INHALED, INGESTED/CONTACTED W/SKIN OR EYES. OVEREXP TO MANGANESE
CMPDS HAVE (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:BEEN SHOWN TO PRDCE EFTS ON CNS & RED
BLOOD CELL COUNTS. CONC NITRIC ACID MAY BE FATAL IF TOO MUCH
INHALED/ABSORBED THRU SKIN. CONC NITRIC ACID VAP/MIST IS IRRIT OF
EYES, MUC MEMBS & SKIN. IN CONT W/EYES, IT PRDCES SEV BURNS
WHICHMAY RSLT IN PERM DMG & VISUAL IMPAIRMENT. ON SKIN, LIQ/CONC
VAP PRDCES (ING 5)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:EYES:FLUSH W/WATER FOR AT LEAST 15 MINUTES OCCASIONALLY
LIFTING UPPER & LOWER EYELIDS. SKIN:REMOVE CONTAMINATED CLOTHING,
THEN FLUSH W/WATER FOR AT LEAST 15 MINUTES. WASH CLOTHING
THOROUGHLY BEFORE RE USE. INHAL:MOVE TO FRESH AIR. INGEST:DONOT
INDUCE VOMITING. GET IMMEDIATE MEDICAL HELP. IF PATIENT IS
CONSCIOUS, GIVE LARGE QUANTITIES OF WATER OR MILK. IF IRRITATION
CONTINUES, GET MED ATTN IMMED.

Extinguishing Media:APPROPRIATE TO SURROUNDING FIRE CONDITIONS.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:CONC HNO*3 REACTS EXPLOSIVELY W/COMBUST
ORG/READILY OXIDIZABLE MATLS SUCH AS; ALCOHOL, WOOD, TURPENTINE,
METAL PWDRS, HYDROGEN SULFIDE, ETC. CONC HNO*3 (SUPDAT)

Spill Release Procedures:VENTILATE AREA. DILUTE SPILL W/WATER & NEUT
W/SODA ASH, LIMESTONE, ETC. WIPE UP & PUT INTO SEALED CNTNR FOR
PROPER DISP. WASH SPILL SITE OFF W/WATER AFTER MATL PICK UP IS
COMPLETE. WEAR CHEM RESIST GL ASSES, GLOVES & CLTHG. WEAR NIOSH
APPRVD RESP.
Neutralizing Agent:SODA ASH, LIMESTONE, ETC.

Handling and Storage Precautions:CONCENTRATED NITRIC ACID WILL ATTACK
SOME FORMS OF PLASTICS, RUBBER & COATINGS. STORE AT ROOM
TEMPERATURE. KEEP TIGHTLY SEALED WHEN NOT IN USE.
Other Precautions:IRRITANT, OXIDIZER & CORROSIVE. AVOID INHALATION,
INGESTION & CONTACT W/EYES & SKIN.

Respiratory Protection:WEAR NIOSH APPROVED RESPIRATOR.
Ventilation:USE IN A CHEMICAL FUME HOOD.
Protective Gloves:CHEMICAL RESISTANT GLOVES.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGS &(SUPDAT)
Other Protective Equipment:ANSI APPROVED EYE WASH FOUNTAIN & DELUGE
SHOWER . WEAR CHEMICAL RESISTANT CLOTHING. LAB COAT.
Work Hygienic Practices:WASH CAREFULLY AFTER USE.
Supplemental Safety and Health
MFR'S TRADE NAME/PART NO:OF MANGANESE IN 5% NITRIC ACID. EYE PROT:FULL
LGTH FSHLD . EXPLO HAZ:IS NOT COMBUST, BUT IS STRONG OXIDIZER & ITS
HEAT OF RXN W/REDUCING AGENTS/COMBUSTS MAY CAUSE IGNIT. CAN REACT
W/METALS TO RELS FLAMM HYDROGEN GAS. MATLS TO AVOID:ALCOHOL, WOOD,
TURPENTINE, METAL POWDERS, HYDROGEN(ING 4)

Spec Gravity:1
Solubility in Water:SOLUBLE
Appearance and Odor:TRANSPARENT W/ACRID ODOR.

Stability Indicator/Materials to Avoid:YES
CONC HNO*3 IS A POWERFUL OXIDIZING AGENT. IT REACTS EXPLOSIVELY
W/COMBUST ORG/READILY OXIDIZABLE MATLS SUCH AS; (SUPDAT)
Stability Condition to Avoid:ELEVATED TEMPERATURES MAY CAUSE CONTAINERS
TO BURST & LIBERATE TOXIC OXIDES OF NITROGEN.
Hazardous Decomposition Products:WILL RELEASE TOXIC NITROGEN OXIDE
FUMES & VAPORS.

Waste Disposal Methods:DISPOSAL MUST BE I/A/W FEDERAL, STATE & LOCAL
REGULATIONS . CONTACT LOCAL HAZARDOUS OR CHEMICAL WASTE DISPOSAL
AGENCY FOR REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.